Nd:YLF Crystal Neodymium-doped yttrium lithium fluoride

Nd:YVO4 (Neodymium Doped Yttrium Orthovanadate) crystals is one of the most promising commercially available diode pumped solid state laser materials, especially, for low to middle power density. This is mainly for its higher absorption and emission features than Nd:YAG crystal. Pumped by laser diodes, Nd:YVO4 crystal has been incorporated with high NLO coefficient crystals ( LBO, BBO, or KTP) to frequency-shift the output from the near infrared to green, blue, or even UV. This incorporation to construct all solid state lasers is an ideal laser tool that can cover the most widespread applications of lasers, including machining, material processing, spectroscopy, wafer inspection, light displays, medical diagnostics, laser printing, and data storage, etc. It has been shown that Nd:YVO4 based diode pumped solid state lasers are rapidly occupying the markets traditionally dominated by water-cooled ion lasers and lamp-pumped lasers, especially when compact design and single-longitudinal-mode outputs are required.

Nd:GdVO4, is a promising material for diode pumped lasers. Similar to the more well-known Nd:YVO4 crystal, Nd:GdVO4 crystal also exhibits high gain, low threshold, and high absorption coefficients at pumping wavelengths. Nd:GdVO4 has the additional advantage over Nd:YVO4 of a much higher thermal conductivity. For CW lasing at 1.06 um and 1.34 um and intracavity doubling with KTP and LBO, the gadolinium vanadate have produced a higher slope efficiency or optical conversion than Nd:YVO4.

Nd:YAG is the earliest and most famous laser host crystal. Since it combines great advantages in many basic properties,Nd:YAG is the ubiquitous presence for near-infrared solid-state lasers and their frequency-doubler, tripler, and higher order multiplier. It is widely used in industrial, medical, military and scientific fields.. Nd:YAG crystals are wildly used in all types of solid-state laser systems-frequency-doubled continuous wave, high-energy Q-switched, and so forth.Its good fluorescent lifetime thermal conductivity and physical strengths makes it suitable for high power lamp pumped laser.

YbYAG crystal is more suitable for diode-pumping than the traditional Nd-doped systems. It can be pumped at 0.94 μm laser output. Compared with the commonly used Nd:YAG crystal, Yb:YAG crystal has a much larger absorption bandwidth to reduce thermal management requirements for diode lasers, a longer upper-state lifetime, three to four times lower thermal loading per unit pump power. Yb:YAG crystal is expected to replace Nd:YAG crystal for high power diode-pumped lasers and other potential applications.

HGO grows Pr:YLF laser crystals using Czochralski technology. Pr3+:YLF has been found as promising laser material for producing visible lasers directly and UV lasers through intracavity second-harmonic generation. Very few laser materials have the necessary properties for the realization of lasing in the visible spectral range. Trivalent praseodymium (Pr3+) is known to be an interesting laser ion for use with solid-state lasers in the visible spectral range because of its energy levels scheme, providing several transitions in the red (640 nm, 3P0 to 3F2), orange (607 nm, 3P0 to 3H6), green (523 nm, 3P0 to 3H5), and dark red (720 nm, 3P0 3F3+3F4) spectral regions.

HGO grows Ho:YLF laser crystals using Czochralski technology. Ho:YLF is a very attractive laser material, because the lifetime of the upper laser level is much longer ( ~ 14 ms) than in Ho:YAG and the emission cross sections are higher. Additionally the thermal lens in Ho:YLF is much weaker, which helps to generate diffraction limited beams even under intense end-pumping. The primary advantage of directly pumping the Ho 5I7 is that it does not have to depend on energy transfer, which lends itself to various radiative and non-radiative losses. Up-conversion losses that have deleterious effect in high-energy Q-switched lasers are eliminated.

HGO grows Tm:YLF laser crystals using Czochralski technology. Tm:YLF is an important middle infrared laser crystal. Because Tm:YLF is negative uniaxial crystal, whose thermal refractive index coefficient is negative, some thermal distortion may be counteracted and high-quality light can be output. Conveniently pumped at 792nm, 1.9μm linearly polarized beam is output in a axis, and non-linearly polarized beam is output in c axis. The YLF crystals has low non-linear refraction index value and thermo optical constants, which makes these crystals applicable in research, development, education, production, photonics, optic, laser technology and telecommunications. Besides, Tm3+:YLF lasers are ideal pump sources for 2.1 μm Ho3+:YAG lasers. This is due to a good overlap of Tm3+:YLF emission and Ho3+:YAG absorption spectra and the capacity of producing linearly polarized output. What is more, the refractive index of Tm3+:YLF decreases with temperature, leading to a negative thermal lens that is partly compensated by a positive lens effect due to end face bulging.

Ti:Sapphire crystal is the most widely used tunable solid-state laser material combining the supreme physical and optical properties with the extremely broad lasing range. Its lasing bandwidth can support pulses < 10fs making it the crystal of choice for femtosecond mode-locked oscillators and amplifiers. The absorption band of Ti:Sapphire centers at ~ 490 nm so it may be conveniently pumped by various laser sources such as argon ion lasers or frequency doubled Nd:YAG, Nd:YLF, Nd:YVO4 lasers at ~530nm. Laser designers are using Ti:sapphire to generate femtosecond pulses to create new industrial tools. A properly delivered femtosecond laser pulse interacts within the target leaving the surrounding area undisturbed. Newly developed femtosecond pulsed lasers micro-machine complex fine structures in glass, metal and other materials. Active waveguides can be written below the surface, integrating optical devices within the body of a substrate. Defects in photomasks can be repaired without disturbing neighbouring patterns. And it is now possible to achieve cellular resolution in vivo for medical diagnosis with femtosecond pulse lasers.